Is There Evidence for Non-linear Thiocyanate or Selenocyanate Ions?
نویسنده
چکیده
The structure of a mixed-valence copper complex with 1,10phenanthroline, [Cu(phen)2]±NC±[Cu (phen)((Se,S)CN)][(Se,S)CN].0.5(C2H5OH), -cyano-1 N:2 C-(seleno,thio)cyanato-2 N-tris(1,10-phenanthroline)-1 4N,N0;2 2N,N0-dicopper(I,II) (seleno,thio)cyanate semiethanolate, has been revised from space group Cc to C2/c. Re®nement in C2/c has shown that, contrary to the Cc results, the (Se,S)CN anions can be described as approximately linear, as expected.
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